Zogulitsa zathu zazikulu: Amino silikoni, silikoni chipika, silikoni hydrophilic, onse a silikoni emulsion awo, nyongolotsi akusisita fastness improver, madzi othamangitsa (Fluorine free, Mpweya 6, Mpweya 8), demin kutsuka mankhwala (ABS, Enzyme, Spandex mtetezi, Manganese remover) , Maiko otumiza kunja: India, Pakistanrk, Bangladesh, Türkçe

 

Emulsifiers akhoza kugawidwa m'magulu awiri kutengera magwero awo: zinthu zachilengedwe ndi zinthu zopangidwa. Malinga ndi katundu wa emulsion dongosolo anapanga mu magawo awiri, izo zikhoza kugawidwa mu mitundu iwiri: madzi mu mafuta (O/W) mtundu ndi madzi mu mafuta (W/O) mtundu.

Chizindikiro chomwe chimagwiritsidwa ntchito kwambiri poyeza magwiridwe antchito a emulsifying ndi mtengo wa hydrophilic lipophilic balance (HLB). Mtengo wotsika wa HLB umasonyeza kuti emulsifier ali ndi lipophilicity yamphamvu ndipo amatha kupanga madzi mu mafuta (W / O); Mtengo wapamwamba wa HLB umasonyeza hydrophilicity yamphamvu ndipo imakonda kupanga mafuta m'madzi (O/W). Chifukwa chake, mtengo wa HLB uli ndi chowonjezera china, chomwe chitha kugwiritsidwa ntchito pokonzekera mafuta odzola okhala ndi mitundu yosiyanasiyana yamtengo wa HLB.

 

[Mtundu wa emulsifier]

Mamolekyu a emulsifier ali ndi zigawo ziwiri zakumaloko, hydrophilic ndi lipophilic. Malingana ndi makhalidwe awo amtundu wa hydrophilic, amatha kugawidwa m'magulu atatu.

1.Negative ion emulsifiers ndi emulsifiers kuti ionize m'madzi kuti apange magulu olakwika a ion hydrophilic okhala ndi magulu a alkyl kapena aryl, monga carboxylates, sulfates, ndi sulfonates. Ma emulsifier amtunduwu amagwiritsidwa ntchito kwambiri ndipo amakhala ndi voliyumu yapamwamba kwambiri yopanga. Zomwe zimagwiritsidwa ntchito nthawi zambiri ndi sopo (C15-17H31-35CO2Na), sodium stearate (C17H35CO2Na), sodium dodecyl sulfate (C12H25OSO3Na), ndi calcium dodecyl benzene sulfonate (chilinganizo cha zomangamanga: [ikani chilinganizo]). Ma ion emulsifiers oyipa amafunikira kuti agwiritsidwe ntchito pansi pamikhalidwe yamchere kapena yosalowerera ndale ndipo sangagwiritsidwe ntchito pansi pa acidic. Pamene mitundu yosiyanasiyana ya emulsifiers imagwiritsidwa ntchito pokonzekera mafuta odzola, ma emulsifiers a anionic amatha kusakaniza wina ndi mzake kapena ndi emulsifiers nonionic. Ma ion oipa ndi ma emulsifiers abwino sangagwiritsidwe ntchito palimodzi mu emulsion imodzi, monga kusakaniza kungasokoneze kukhazikika kwa emulsion.

2. Positive ion emulsifiers ionize m'madzi kuti apange magulu abwino a ion hydrophilic ndi magulu a alkyl kapena aryl. Pali mitundu yochepa ya mtundu uwu wa emulsifier, ndipo zonsezi ndi zochokera ku amines, monga N-dodecyldimethylamine, zomwe zingagwiritsidwe ntchito polima.

3.Non ionic emulsifiers ndi mtundu watsopano wa emulsifier wodziwika ndi osakhala ionization m'madzi. Dera lake la hydrophilic limapangidwa ndi magulu osiyanasiyana a polar, makamaka kuphatikiza ma polyoxyethylene ethers ndi polyoxypropylene ethers. Lipophilic moiety yake (alkyl kapena aryl) imamangiriza mwachindunji ku mgwirizano wa ethylene oxide ether. Chinthu chodziwika bwino ndi para octylphenol polyoxyethylene ether (chilinganizo chokhazikika:). Ma atomu a okosijeni pamaketani a polyether a emulsifiers omwe si a ionic amatha kupanga zomangira za haidrojeni ndi madzi, kuwalola kusungunuka m'madzi. Itha kugwiritsidwa ntchito pansi pa zinthu za acidic ndi zamchere, ndipo imakhala ndi emulsification yabwino. Amagwiritsidwa ntchito kwambiri popanga mankhwala, nsalu, mankhwala ophera tizilombo, petroleum, ndi latex.

 

Mitundu ya emulsifiers

 

Gulu 1: Opanda ma ionic surfactants

 

1, Etere yochokera zowonjezera zopanda ma ionic

1. Alkylphenol polyoxyethylene ether

1) Nonylphenol polyoxyethylene etha NP mndandanda, Nongfu No.

2) Octylphenol polyoxyethylene etha emulsifier OP mndandanda, phosphooctyl 10 (sec octylphenol polyoxyethylene ether)

3) Bis, tributylphenol polyoxyethylene ether (C4H9) - O (EO) nH

4) Alkylphenol polyoxyethylene etha polyoxyethylene propylene etha emulsifier No.

5) Phenethyl phenol polyoxypropylene polyoxyethylene etha emulsifier No.

 

2. Benzylphenol polyoxyethylene ether

1) 2. Tribenzyl phenol polyoxyethylene etha emulsifier BP, Wulu BP, mtambo mfundo 65-70 ℃

2) Dibenzylphenol polyoxyethylene etha Nongyu 300

3) Benzyl dimethyl phenol polyoxyethylene etha Nongyu 400

4) Dibenzyl isopropylphenyl phenol [yemwe imadziwikanso kuti dibenzyl diphenol] polyoxyethylene etha emulsifier BC mtambo mfundo 69-71 ℃

5) Dibenzylbiphenylphenol, polyoxypropylene, polyoxyethylene ether, Ningru 31, cloud point 76-84 ℃, mlingo wochepa, kugwiritsidwa ntchito kwakukulu

 

3. Phenethyl phenol polyoxyethylene ether

1) Phenethyl phenol polyoxyethylene ether mkaka waulimi No. 600 ndi No. Pali mitundu iwiri:

Triphenylethylphenol polyoxyethylene ether, yomwe imapezeka muzinthu zitatu

Triphenylethylphenol/epoxyethane (mass ratio) Cloud point (1% aqueous solution) Nambala yowonjezera ya EO

1:2.2-2.3 70-75 20-21 1:2.6-2.7 80-85 24-25
1:3.2-3.3 95-100 30-31
Bisphenethyl phenol polyoxyethylene ether

2) Phenethyl isopropylphenyl phenol polyoxyethylene etha mkaka waulimi 600-2 intermediate/EO mass ratio cloud point (1% aqueous solution) EO nambala yowonjezera
1:2.1-2.3 70-75 17-18 1:2.6-2.8 85-90 20-24

3) Diphenylethyl phenol polyoxyethylene etha emulsifier BS ili ndi zinthu zabwino zopangira emulsifying ndi 500 mankhwala opha tizilombo a phosphorous. Kuchuluka kwapakati/EO ndi 1:1.7 1:2 1:2.3 1:2.6 1:3 1:3.5 1:4 mtambo mfundo (1% yankho lamadzi) 51 70 75 82 89 96 86 (5% CaCl2 yankho)

4) Diphenylethyldiphenol polyoxyethylene ether

5) Phenethyl naphthol polyoxyethylene ether

 

4. Mowa wochuluka wa polyoxyethylene ether ndi mankhwala ofanana

1) Lauryl mowa polyoxyethylene ether, panopa amapangidwa makamaka kokonati mafuta mowa [makamaka wopangidwa ndi C12 mowa], ndi lolowera wothandizira JFC mtambo mfundo ya 40-50 ℃ ndi malowedwe wothandizira EA.

2) Isooctyl polyoxyethylene etha Igepal CA

3) Octadecanol yochokera polyoxyethylene efa Pingjia mndandanda waulimi mkaka No. 200

4) Etriol polyoxyethylene etha Hirst GenapolX mndandanda Japanese othandizira umagwirira Softanol mndandanda

6) Mowa wochuluka wa polyoxyethylene ether

 

5. Phenethyl phenol polyoxyethylene etha polyoxyethylene propylene etha ndi mankhwala ofanana

1) Phenethyl phenol polyoxyethylene etere EPE mtundu wa ulimi mkaka 1601 Ningru 33 ntchito pophatikiza 1656L/1656H, PEP mtundu ulimi mkaka 1602 Ningru 34 ntchito poonjezera Ningru 0211/0212

2) Phenethyl phenylpropanol polyoxyethylene etha ulimi mkaka 1601-II mtambo mfundo 79-80 ℃, 1602- Ⅱ ℃

3) Phenethyl phenol polyoxyethylene ether

 

6. Mafuta a amine polyoxyethylene ether

1) Mafuta a amine [omwe amadziwikanso kuti alkyl amine] polyoxyethylene ether

2) Mafuta a amide polyoxyethylene ether

3) Alkylamine oxide

4) Quaternary amine alkoxides ndi mankhwala ofanana
Gulu lachiwiri:

Zowonjezera zopanda ionic ester

1. Mafuta a asidi ethylene oxide adduct
1) Oleic acid polyoxyethylene ester
2) Stearic acid polyoxyethylene ester
3) Rosin asidi polyoxyethylene ester

2. Castor mafuta epoxyethane adduct ndi zotuluka zake, emulsifiers m'nyumba ndi dzina lachilendo BL, Ningru 110 120 130 140 emulsifiers EL, PC

3. Polyol fatty acid esters ndi epoxyethane awo adducts dehydrated sorbitol fatty acid esters: Span series 20 40 60 80 85 Strong lipophilicity
Dehydrated sorbitol fatty acid ester epoxyethane adduct: Pakati pa mndandanda uli ndi kusungunuka kwamadzi kwakukulu kuposa Span

4. Zosakaniza zopanda ma ionic zochokera ku glycerol monga zopangira zofunikira

1) Dimeric glycerol ndi mafuta acid esters

2) Diglyceride polypropylene glycol ether

3) Glycerol polyoxyethylene etha polyoxyethylene propylene etha mafuta acid ester
Gulu lalikulu lachitatu:

Zowonjezera zopanda ma ionic okhala ndi midadada ya hydroxyl yothetsedwa
1. Chowonjezera chosakhala ndi ionic chokhala ndi mawonekedwe ofananira komanso kutseka kwa gulu la hydroxyl
2. Zowonjezera zopanda ma ionic zomwe zili ndi mawonekedwe asymmetric ndi kutseka kwa gulu la hydroxyl

 

Anionic surfactant

 

1, Sulfonic acid mchere

 

1. Alkylbenzene sulfonate

1) sodium Dialkylbenzenesulfonate

2) Sodium alkyl aryl sulfonate

3) sodium dodecylbenzenesulfonadadya (calcium) DBS Na

 

2. Alkyl naphthalene sulfonate

1) Sodium butyl naphthalene sulfonate Nekal A chonyowetsa wothandizira HB

2) Sodium dibutyl naphthalene sulfonate Nekal BX (ufa)

3) Sodium diisopropylnaphthalene sulfonate Morwet RP

4) Monomethyl naphthalene sulfonate sodium Morwet M

 

3. Alkyl sulfonate

1) Sodium petroleum sulfonate R ndi gulu losakanikirana la alkili lomwe lili ndi kulemera kwapakati kwa 400-500.

2) Sodium Alkenyl Sulfonate RCH=CHCH2SO3Na

3) sodium hydroxyalkylsulfonate R-CH-CH2-CH2SO3NaOH

 

4. Alkyl succinate sulfonate

1) Sodium alkyl succinate sulfonate penetrant T, wetting agent CB-102 (diisooctylsuccinate sulfonate), Aerosol IB (sodium dibutyl succinate sulfonate), Aerosol MA (sodium dihexyl succinate sulfonate), Aerosol Ay (sodium dipentyl succinate)

2) Alkyl polyoxyethylene etha succinate sulfonate

3）Alkylphenol polyoxyethylene etha succinate sulfonate SSOPA (Alkylphenol polyoxyethylene etha formaldehyde condensate sodium succinate sulfonate) Agricultural Assistance 2000 (monoalkylphenyl polyoxyethylene sulfonate 30% yankho ndi mankhwala a monoalkylphenyl sulfonate 30% succinate)

 

5. Alkyl biphenyl ether sulfonate

 

6. Naphthalene sulfonic acid formaldehyde condensate

1) Dispersant F kwa benzyl naphthalene sulfonate formaldehyde condensate

2) Sodium naphthalene sulfonate formaldehyde condensate NNO

3) Sodium dibutylenesulfonate formaldehyde condensate dispersant NO

4) Methyl naphthalene sulfonate sodium formaldehyde condensate MF

 

7. N-methyl fatty amide based bovine sulfonate detergent 209 pancreatic float T

8. N-alkylacyl sarcosinate Lissapol LS detergent

9.Isopropyl sulfate zotumphukira

 

2, sulphate

1. Sulfated castor mafuta Türkiye mafuta ofiira

2. Mafuta a mowa sulphate ROSO3Na

1) Kusinthidwa kwa Sodium Lauryl Sulfate

2) Sodium cetamol sulphate C16H33SO3Na

3) Sodium yachiwiri mowa sulphate H2n+1CH (CH3) OSO3Na

4) Mafuta osakaniza mowa (C12-14) sodium sulfate

3. Mowa wochuluka wa polyoxyethylene etha sulfate Maprofix ES (sodium lauryl alcohol polyoxyethylene ether sulfate)
4. Alkyl phenol polyoxyethylene etha sulfate RO (EO) nSO3Na magulu a alkyl omwe amagwiritsidwa ntchito kwambiri ndi nonyl ndi octyl.

5. Onunkhira alkylphenol polyoxyethylene etha sulphate

3. Phosphate ndi hypophosphite

1. Alkylphenol polyoxyethylene etha phosphate OO RO (EO) np - (OH) 2 [RO (EO) n] 2-P - (OH) 2 monoester diester
Pano pali mitundu iwiri: R=C8H17 OPEPO4 ndi R=C9H19 NPEPO4
Dzina lazogulitsa: Phenolic Etha Phosphate Surfactant MAPP (Monoester), NPEPO4Na (kapena K)

2.Phenethylphenol polyoxyethylene etha phosphate ester (mtundu wa asidi wopanda) kodi SPEnPO4 O [- CHCH3] KO (EO) np - (OH) 2 [[- CHCH3] KO (EO) n] 2-P - (OH) 2 monoester diester

3. Mafuta a asidi polyoxyethylene ester phosphate
4. Alkyl phosphate, aryl phosphate O
5. Alkylamine polyoxyethylene etha phosphate ester R=C12-14 n=10-16 monoester, yomwe imadziwikanso kuti surfactant MAPRO (EO) np - (OH) 2
6. Mowa wochuluka wa polyoxyethylene etha phosphate ester
4, Carboxylate (mafuta carboxylate) monga rosin asidi sopo polima zowonjezera

1, Non-ionic mtundu
1. Alkylphenol polyoxyethylene etha formaldehyde condensate Nongfu 700

2. 1) Phenylalkylphenol polyoxyethylene etha formaldehyde condensate Ningru No. 36, Nongli No. 700-1 Nongli SPF 2) Isopropylphenol polyoxyethylene ether formaldehyde condensate Nongli No. 700-2.37 3) Benzylphenol polyoxyethylene etha formaldehyde condensate Japan Sorpol PPB150, 200

1) Phenethyl phenol polyoxyethylene etha formaldehyde condensate Ningru 36 ndi Nongfu 700-1 Nongfu SPF

2) Isopropyl phenyl phenol polyoxyethylene etha formaldehyde condensate Nongjiu 700-2 ndi Ningru 37

3) Benzylphenol polyoxyethylene etha formaldehyde condensate Japan Sorpol PPB150,200

3. Biphenylphenol polyoxyethylene etha formaldehyde condensate

4. Polyvinyl mowa ndi hydrolysis wathunthu ndi 98-99%, ndi digiri ya hydrolysis ndi tsankho hydrolysis ndi 88-89%

5. Polyoxyethylene ndi polyoxypropylene block copolymers, okhala ndi ma polyether molecular weight 2000-3000, ali ndi mphamvu yabwino yoyeretsa, ndipo zolemera zapamwamba za maselo zimakhala ndi dispersibility bwino, monga epoxyethane epoxybutane copolymer ndi epoxyethane epoxypropane epoxybutane copoxybutane copolymer.

2, mtundu wa anionic
1. Polycarboxylate polyacrylic acid, sodium polyacrylate, polyacrylamide

2. Alkylphenol polyoxyethylene etha formaldehyde condensate sulfate SOPA-II (270) SOPA-V (570)

3. Alkyl naphthalene sulfonate formaldehyde condensate ndi mitundu yake yofananira MF MSF
4. Phenol formaldehyde condensate sulfonate ndi mitundu yake yofananira
5. Methylcellulose ndi zotumphukira zake
6. Xanthan chingamu XG
7. Lignosulfonate Sodium Lignosulfonate M-9, 16 Deglycosylated Sodium Lignosulfonate M-10 Lignosulfonate Sodium M-14 Condensed Modified Sodium Lignosulfonate M-13, 15 Deglycosylated Sodium Lignosulfonate M-17

cationic surfactant

1, Ammonium mchere mtundu

1. Mtundu wa mchere wa Alkyl ammonium

2. Amino mowa mafuta asidi otumphukira mtundu

3. Polyamine mafuta asidi otumphukira mtundu
4. Mtundu wa Imidazoline

2, mtundu wa mchere wa Quaternary ammonium

1. Alkyl trimethylammonium mchere wamtundu wa dodecyl trimethylammonium chloride 1231 Hexadecyltrimethylammonium chloride 1631 Octadecyltrimethylammonium chloride 1831
2. Mtundu wa mchere wa Dialkyldimethylammonium
3. Alkyl dimethyl benzyl ammonium mchere wamtundu wa dodecyl dimethyl benzyl ammonium chloride 1227 acrylic dyeing agent TAN
4. Mtundu wa mchere wa Pyridine
5. Alkyl isoquinoline mchere mawonekedwe
6. Benzyl kloride mtundu wa amine

Amphoteric surfactant

1, mtundu wa amino acid

1. Mtundu wa Alanine

2. Glycine mtundu II, betaine mtundu III, imidazoline mtundu IV, ndi okusayidi amine ndi ofanana amphoteric surfactants, n'zogwirizana ndi onse anionic surfactants ndi cationic ndi nonionic surfactants. Amawonetsa zinthu zopanda ma ionic munjira zapakatikati ndi zamchere komanso zofooka za cationic munjira za acidic.

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